9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers

被引：163

作者：

Lorbach, Andreas ^{[1
]}

Bolte, Michael ^{[1
]}

Li, Haiyan ^{[2
]}

Lerner, Hans-Wolfram ^{[1
]}

Holthausen, Max C. ^{[1
]}

Jaekle, Frieder ^{[2
]}

Wagner, Matthias ^{[1
]}

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

[2] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 25期

关键词：

boron; fluorescence; hydroboration; organoboranes; polymers; 3-COORDINATE ORGANOBORON COMPOUNDS; AMORPHOUS MOLECULAR MATERIALS; BRIDGED POLY(FERROCENYLENE)S; HYDROBORATION POLYMERIZATION; ELECTROLUMINESCENT DEVICES; BORON ATOM; BINDING; SYSTEMS; FAMILY; ACID;

D O I：

10.1002/anie.200901226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Building bridges: The title compound forms an unprecedented polymeric structure with bridging B-H-B three-center two-electron bonds in the solid state. This organoborane serves as an efficient precursor for the preparation of boron-doped π-conjugated polymers by hydroboration polymerization with a functionalized 1,4-diethynylbenzene (see picture). These polymers form thin films that show intense green luminescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4584 / 4588

页数：5

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