Unexpected scenario of glass transition in polymer globules: An exactly enumerable model

被引:12
作者
Du, R
Grosberg, AY
Tanaka, T
Rubinstein, M
机构
[1] MIT, Dept Phys, Cambridge, MA 02139 USA
[2] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA
[3] Univ Minnesota, Dept Phys, Minneapolis, MN 55455 USA
[4] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.84.2417
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We introduce a lattice model of glass transition in polymer globules. This model exhibits ergodicity breaking in which the disjoint regions of phase space do not arise uniformly, but as small chambers whose number increases exponentially with polymer density. Chamber sizes obey power law distribution, making phase space similar to a fractal foam. This clearly demonstrates the importance of the phase space geometry and topology in describing any glass-forming system, such as semicompact polymers during protein folding.
引用
收藏
页码:2417 / 2420
页数:4
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