Structure and phase behavior of a 2:1 complex between arene- and fluoroarene-based conjugated rigid rods

被引:127
作者
Watt, SW
Dai, C
Scott, AJ
Burke, JM
Thomas, RL
Collings, JC
Viney, C
Clegg, W
Marder, TB [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Heriot Watt Univ, Sch Engn & Phys Sci, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[3] Newcastle Univ, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
[4] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
关键词
crystal engineering; fluorine; liquid crystals; pi interactions; supramolecular chemistry;
D O I
10.1002/anie.200453828
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The πs have it: An unusual 2:1 areneperfluoroarene π complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.
引用
收藏
页码:3061 / 3063
页数:3
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