Molecular theory of hydrophobic effects: "She is too mean to have her name repeated."

被引：284

作者：

Pratt, LR ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 2002年 / 53卷

关键词：

aqueous solutions; biomolecular structure; statistical thermodynamics; quasichemical theory; pressure denaturation;

D O I：

10.1146/annurev.physchem.53.090401.093500

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reviews the molecular theory of hydrophobic effects relevant to biomolecular structure and assembly in aqueous solution. Recent progress has resulted in simple, validated molecular statistical thermodynamic theories and clarification of confusing theories of decades ago. Current work is resolving effects of wider variations of thermodynamic state, e.g., pressure denaturation of soluble proteins, and more exotic questions such as effects of surface chemistry in treating stability of macromolecular structures in aqueous solution.

引用

页码：409 / 436

页数：28

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