Singlet exciton transfer and fullerene triplet formation in polymer-fullerene blend films

被引:67
作者
Cook, Steffan
Ohkita, Hideo
Durrant, James R. [1 ]
Kim, Youngkyoo
Benson-Smith, Jessica J.
Nelson, Jenny
Bradley, Donal D. C.
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Phys, London SW7 2BW, England
基金
英国工程与自然科学研究理事会; 日本学术振兴会;
关键词
D O I
10.1063/1.2338528
中图分类号
O59 [应用物理学];
学科分类号
摘要
Photoluminescence and transient absorption measurements of poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)C-61 (PCBM) blend films reveal that optical excitation of F8BT results in formation of the singlet and triplet excited states of PCBM. These observations are assigned to rapid (> 10(11) s(-1)) singlet energy transfer from F8BT to PCBM, followed by intersystem crossing to the PCBM triplet state. (c) 2006 American Institute of Physics.
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页数:3
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共 18 条
  • [1] Acceptor influence on hole mobility in fullerene blends with alternating copolymers of fluorene
    Andersson, LM
    Inganäs, O
    [J]. APPLIED PHYSICS LETTERS, 2006, 88 (08)
  • [2] Intra- and intermolecular photoinduced energy and electron transfer between oligothienylenevinylenes and N-methylfulleropyrrolidine
    Apperloo, JJ
    Martineau, C
    van Hal, PA
    Roncali, J
    Janssen, RAJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (01) : 21 - 31
  • [3] Bensasson RV, 1998, CHEM-EUR J, V4, P270, DOI 10.1002/(SICI)1521-3765(19980210)4:2<270::AID-CHEM270>3.0.CO
  • [4] 2-5
  • [5] BENSONSMITH JJ, UNPUB ADV FUNCT MAT
  • [6] Control of phase separation in blends of polyfluorene (co)polymers and the C60-derivative PCBM
    Björström, CM
    Magnusson, KO
    Moons, E
    [J]. SYNTHETIC METALS, 2005, 152 (1-3) : 109 - 112
  • [7] Quantifying the efficiency of electrodes for positive carrier injection into poly(9,9-dioctylfluorene) and representative copolymers
    Campbell, AJ
    Bradley, DDC
    Antoniadis, H
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 89 (06) : 3343 - 3351
  • [8] Fullerene-oligophenylenevinylene hybrids: Synthesis, electronic properties, and incorporation in photovoltaic devices
    Eckert, JF
    Nicoud, JF
    Nierengarten, JF
    Liu, SG
    Echegoyen, L
    Barigelletti, F
    Armaroli, N
    Ouali, L
    Krasnikov, V
    Hadziioannou, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (31) : 7467 - 7479
  • [9] Solvent polarity dependence of photoinduced charge separation in a tetrathiophene-C60 dyad studied by pico- and nanosecond laser flash photolysis in the near-IR region
    Fujitsuka, M
    Ito, O
    Yamashiro, T
    Aso, Y
    Otsubo, T
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (21) : 4876 - 4881
  • [10] Charge separation versus recombination in dye-sensitized nanocrystalline solar cells: the minimization of kinetic redundancy
    Haque, SA
    Palomares, E
    Cho, BM
    Green, ANM
    Hirata, N
    Klug, DR
    Durrant, JR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) : 3456 - 3462