Experiments on the pyrolysis of large beechwood particles in fixed beds

被引:53
作者
Schröder, E [1 ]
机构
[1] Forschungszentrum Karlsruhe, Inst Nucl & Energy Technol, D-76021 Karlsruhe, Germany
关键词
pyrolysis; fixed bed; biomass; wood;
D O I
10.1016/j.jaap.2003.09.004
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Fixed beds of beechwood particles 10 mm in size were pyrolyzed under conventional pyrolysis conditions. For this purpose, the beds were heated to a maximum temperature of 525 degreesC at rates 3-10 K/min by a flow of hot nitrogen. The loss of mass of the beds in the decomposition process was recorded as a function of time in addition to the temperature field inside the beds, which was measured continuously. The yields of char, tar and gas were quantified, and the composition of the products was analyzed with respect to their elemental composition and calorific values at various temperatures. The results are compared with the findings made in various studies of this topic. The results are an important tool for validating physical and chemical models of heating, drying, and pyrolyzing fixed beds of biomass. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:669 / 694
页数:26
相关论文
共 39 条
[1]   Pyrolysis of sawdust in a conical spouted bed reactor.: Yields and product composition [J].
Aguado, R ;
Olazar, M ;
José, MJS ;
Aguirre, G ;
Bilbao, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (06) :1925-1933
[2]   PYROLYSIS KINETICS OF LIGNOCELLULOSIC MATERIALS [J].
BALCI, S ;
DOGU, T ;
YUCEL, H .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (11) :2573-2579
[3]   Gas formation in the thermal decomposition of large spherical wood particles [J].
Bilbao, R ;
Arauzo, J ;
Murillo, MB ;
Salvador, ML .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1997, 43 (01) :27-39
[4]   TEMPERATURE PROFILES AND WEIGHT-LOSS IN THE THERMAL-DECOMPOSITION OF LARGE SPHERICAL WOOD PARTICLES [J].
BILBAO, R ;
MILLERA, A ;
MURILLO, MB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (09) :1811-1817
[5]   Principles and practice of biomass fast pyrolysis processes for liquids [J].
Bridgwater, AV .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) :3-22
[6]  
BROIDO A, 1966, PYRODYNAMIC, V4, P243
[7]  
Bruch C., 2001, THESIS EIDGENOSSISCH
[8]   SINGLE-PARTICLE BIOMASS PYROLYSIS - CORRELATIONS OF REACTION-PRODUCTS WITH PROCESS CONDITIONS [J].
CHAN, WCR ;
KELBON, M ;
KRIEGERBROCKETT, B .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1988, 27 (12) :2261-2275
[9]   A unified correlation for estimating HHV of solid, liquid and gaseous fuels [J].
Channiwala, SA ;
Parikh, PP .
FUEL, 2002, 81 (08) :1051-1063
[10]  
CHEN GG, 2001, MATH MODELING BIOMAS, P1158