Aqueous degradation and chemical passivation of yttria-tetragonally-stabilized zirconia at 25°C

被引:21
作者
Kimel, RA [1 ]
Adair, JH [1 ]
机构
[1] Penn State Univ, Inst Mat Res, University Pk, PA 16802 USA
关键词
D O I
10.1111/j.1151-2916.2002.tb00288.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The objective of this study was to establish the mechanism(s) controlling degradation of yttria-tetragonally-stabilized zirconia (Y-TZP) powder in aqueous suspensions and determine the significance of this degradation to the aqueous physical chemistry of Y-TZP. Experiments were performed on commercially available Y-TZP powder placed in aqueous suspensions at 25degreesC. Experimental investigations included analysis of the aqueous chemistry of Y-TZP in water via ICP-MS, determination of the surface and bulk structure of the powder via XRD and solid-state NMR, and observation of changes in surface charges via zeta potential determinations. The goal of this study was to control the surface chemistry of Y-TZP in aqueous suspension to promote dispersion and permit aqueous processing of Y-TZP powders.
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页码:1403 / 1408
页数:6
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