C-C bond-forming reductive elimination from a zirconium(IV) redox-active ligand complex

被引：182

作者：

Haneline, Mason R. ^{[1
]}

Heyduk, Alan F. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 26期

关键词：

D O I：

10.1021/ja061107a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-carbon bond-forming reductive elimination of biphenyl is observed upon two-electron oxidation of the [ZrIVPh2(ap)2]2- dianion. Crossover experiments confirm that the C-C bond-forming step occurs at a single zirconium metal center. The reactivity is enabled by the participation of a redox-active amidophenolate ligand set. Copyright © 2006 American Chemical Society.

引用

页码：8410 / 8411

页数：2

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