Recent progress in passive direct methanol fuel cells at KIST

被引:158
作者
Kim, DJ [1 ]
Cho, EA [1 ]
Hong, SA [1 ]
Oh, IH [1 ]
Ha, HY [1 ]
机构
[1] Korea Inst Sci & Technol, Fuel Cell Res Ctr, Seoul 130650, South Korea
关键词
passive DMFC; air-breathing DMFC; monopolar stack; portable power sources; MEA;
D O I
10.1016/j.jpowsour.2003.12.023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper describes recent advances in passive direct methanol fuel cells (DMFCs) at the Korea Institute of Science and Technology (KIST). At KIST, we have been developing passive micro-DMFCs with capacities under 5 W that are expected to be used as portable power sources. Research activities are focused on development of membrane-electrode assemblies (MEAs) and design of monopolar stacks operating under passive and air-breathing conditions. The passive cells showed many unique features, much different from the active ones. Single cells with active area of 6 cm(2) showed a maximum power density of 40 mW/cm(2) at 4 M of methanol concentration at room temperature. A six-cell stack having a total active area of 27 cm(2) was constructed in a monopolar configuration and it produced a power output of 1000 mW (37 mW/cm(2)). Effects of experimental parameters on the performance were also examined to investigate the operation characteristics of single cells and monopoiar stacks. Application of micro-DMFCs as portable power sources were demonstrated using small toys and display panels powered by the passive monopolar stacks. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:172 / 177
页数:6
相关论文
共 17 条
[1]   Carbon dioxide evolution patterns in direct methanol fuel cells [J].
Argyropoulos, P ;
Scott, K ;
Taama, WM .
ELECTROCHIMICA ACTA, 1999, 44 (20) :3575-3584
[2]   Experimental results on the direct electrochemical oxidation of methanol in PEM fuel cells [J].
Baldauf, M ;
Preidel, W .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (07) :781-786
[3]   Materials and processes for small fuel cells [J].
Chang, H ;
Kim, JR ;
Cho, JH ;
Kim, HK ;
Choi, KH .
SOLID STATE IONICS, 2002, 148 (3-4) :601-606
[4]   Performance of an air-breathing direct methanol fuel cell [J].
Chen, CY ;
Yang, P .
JOURNAL OF POWER SOURCES, 2003, 123 (01) :37-42
[5]   Process engineering of the direct methanol fuel cell [J].
Dohle, H ;
Divisek, J ;
Jung, R .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :469-477
[6]   Fuel cells for portable applications [J].
Dyer, CK .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :31-34
[7]   Direct methanol fuel-cell combined with a small back-up battery [J].
Han, J ;
Park, ES .
JOURNAL OF POWER SOURCES, 2002, 112 (02) :477-483
[8]   An electrochemical method to improve the performance of air cathodes and methanol anodes [J].
He, CZ ;
Qi, ZQ ;
Hollett, M ;
Kaufman, A .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (08) :A181-A183
[9]   Fuel cells for low power applications [J].
Heinzel, A ;
Hebling, C ;
Müller, M ;
Zedda, M ;
Müller, C .
JOURNAL OF POWER SOURCES, 2002, 105 (02) :250-255
[10]  
HOCKADAY R, 1999, P C PORT FUEL CELLS, P45