Pericyclic reactions involving catalytic metal-vinylidene complexes

被引：67

作者：

Varela, Jesus A. ^{[1
]}

Saa, Carlos ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Dept Quim Organ, Fac Quim, Santiago De Compostela 15782, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 25期

关键词：

cycloaddition; electrocyclization; metal-vinylidenes; pericyclic reactions; sigmatropic rearrangement;

D O I：

10.1002/chem.200600388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of complex polycyclic systems from terminal alkynes based on the concept of pericyclic reactions of catalytic metal-vinylidenes is presented. Metal-vinylidenes, easily formed from terminal alkynes with catalytic amounts of several metal complexes, can be used in electrocyclizations, cycloadditions or sigma-tropic rearrangements to afford valuable compounds.

引用

页码：6450 / 6456

页数：7

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