A novel pseudo-polyrotaxane structure composed of cyclodextrins and a straight-chain polymer:: Crystal structures of inclusion complexes of β-cyclodextrin with poly(trimethylene oxide) and poly(propylene glycol)

被引:82
作者
Kamitori, S [1 ]
Matsuzaka, O
Kondo, S
Muraoka, S
Okuyama, K
Noguchi, K
Okada, M
Harada, A
机构
[1] Tokyo Univ Agr & Technol, Fac Technol, Dept Biotechnol & Life Sci, Koganei, Tokyo 1848588, Japan
[2] Tokyo Univ Agr & Technol, Instrumentat Anal Ctr, Koganei, Tokyo 1848588, Japan
[3] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 560, Japan
关键词
D O I
10.1021/ma991629t
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An account is given on the crystal structures of inclusion complexes of β-cyclodextrins (CDs) with polymers designated as P3MO and PPG. Both polymers are approximately 97 and 22 angstrom long and may penetrate 14 and three β-CDs, respectively.
引用
收藏
页码:1500 / 1502
页数:3
相关论文
共 14 条
[11]  
Sheldrick G. M., 1997, SHELX97: Program for Crystal Structure Refinement
[12]   ISOSTRUCTURAL REPLACEMENT OF AN N-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O BY A C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BOND IN COMPLEX STABILIZATION - CRYSTAL-STRUCTURES OF BETA-CYCLODEXTRIN COMPLEXED WITH DIETHANOLAMINE AND WITH PENTANE-1,5-DIOL [J].
STEINER, T ;
KOELLNER, G ;
GESSLER, K ;
SAENGER, W .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (05) :511-512
[13]   A VIBRATING FLEXIBLE CHAIN IN A MOLECULAR CAGE - CRYSTAL-STRUCTURE OF THE COMPLEX CYCLOMALTOHEPTAOSE (BETA-CYCLODEXTRIN)-1,4-BUTANEDIOL.6.25H2O [J].
STEINER, T ;
KOELLNER, G ;
SAENGER, W .
CARBOHYDRATE RESEARCH, 1992, 228 (02) :321-332
[14]   A novel mode of inclusion for pyrene in β-cyclodestrin compounds:: The crystal structures of β-cyclodextrin with cyclohexanol and pyrene, and with n-octanol and pyrene [J].
Udachin, KA ;
Ripmeester, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) :1080-1081