Luminescent Anionic Metal-Organic Framework with Potential Nitrobenzene Sensing

被引：139

作者：

He, Yuan-Chun ^{[1
]}

Zhang, Hong-Mei ^{[1
]}

Liu, Ying-Ying ^{[1
]}

Zhai, Qiu-Yi ^{[1
]}

Shen, Qiu-Tong ^{[1
]}

Song, Shu-Yan ^{[2
]}

Ma, Jian-Fang ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 07期

基金：

中国国家自然科学基金;

关键词：

PHOTOLUMINESCENCE; ADSORPTION; LIGAND; SENSOR; SERIES; MOF;

D O I：

10.1021/cg5004353

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Solvothermal reaction of multidentate organic ligand, 5,5',5 '',5 ''',5],5]'-[1,2,3,4,5,6-phenylhexamethoxyl]-hexaisophthalic acid (H12L), with Cd(NO3)center dot 4H(2)O produced an anionic 3D metal-organic framework [(CH3)(2)NH2](4)[Cd-3(H2L)] (1), which features a novel cage-to-cage connection. Interestingly, the 1D channel, which is stacked by cages, is divided into uniform segments by molecular-scale bricks. The luminescent properties of compound 1 have been explored, which shows that 1 is a potential luminescent sensory material for nitrobenzene.

引用

收藏

页码：3174 / 3178

页数：5

相关论文

共 51 条

[1]

Light-emitting molecular devices based on transition metals [J].

Amendola, V ;

Fabbrizzi, L ;

Foti, F ;

Licchelli, M ;

Mangano, C ;

Pallavicini, P ;

Poggi, A ;

Sacchi, D ;

Taglietti, A .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (3-4) :273-299

[2]

Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013) [J].

Batten, Stuart R. ;

Champness, Neil R. ;

Chen, Xiao-Ming ;

Garcia-Martinez, Javier ;

Kitagawa, Susumu ;

Ohrstrom, Lars ;

O'Keeffe, Michael ;

Suh, Myunghyun Paik ;

Reedijk, Jan .

PURE AND APPLIED CHEMISTRY, 2013, 85 (08) :1715-1724

[3]

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].

Bloch, Eric D. ;

Queen, Wendy L. ;

Krishna, Rajamani ;

Zadrozny, Joseph M. ;

Brown, Craig M. ;

Long, Jeffrey R. .

SCIENCE, 2012, 335 (6076) :1606-1610

[4]

Mechanisms for the adsorption of substituted nitrobenzenes by smectite clays [J].

Boyd, SA ;

Sheng, GY ;

Teppen, BJ ;

Johnston, CJ .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (21) :4227-4234

[5]

Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy [J].

Chaemchuen, Somboon ;

Kabir, Nawsad Alam ;

Zhou, Kui ;

Verpoort, Francis .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (24) :9304-9332

[6]

A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[7]

Quantitative structure-activity analyses of nitrobenzene toxicity to Tetrahymena pyriformis [J].

Cronin, MTD ;

Gregory, BW ;

Schultz, TW .

CHEMICAL RESEARCH IN TOXICOLOGY, 1998, 11 (08) :902-908

[8]

Luminescent Functional Metal-Organic Frameworks [J].

Cui, Yuanjing ;

Yue, Yanfeng ;

Qian, Guodong ;

Chen, Banglin .

CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162

[9]

A sense for landmines [J].

Czarnik, AW .

NATURE, 1998, 394 (6692) :417-418

[10]

Lanthanide Metal-Organic Frameworks Showing Luminescence in the Visible and Near-Infrared Regions with Potential for Acetone Sensing [J].

Dang, Song ;

Min, Xue ;

Yang, Weiting ;

Yi, Fei-Yan ;

You, Hongpeng ;

Sun, Zhong-Ming .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (50) :17172-17179

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