Spectroscopic characterization of solvent soluble fractions of petroleum vacuum residues

被引：7

作者：

Sharma, BK ^{[1
]}

Tyagi, OS ^{[1
]}

Aloopwan, MKS ^{[1
]}

Bhagat, SD ^{[1
]}

机构：

[1] CSIR, Indian Inst Petr, Analyt Sci Div, Dehra Dun 248005, Uttar Pradesh, India

来源：

PETROLEUM SCIENCE AND TECHNOLOGY | 2000年 / 18卷 / 3-4期

关键词：

petroleum; vacuum residues; solvent extraction; characterization; NMR; FITR; spectroscopy;

D O I：

10.1080/10916460008949845

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

NMR and FTIR spectroscopic techniques were used to investigate the effect of different solvent extraction schemes on the composition and chemical nature of species of vacuum residues of two Indian crude oils (namely Jodhpur and Heera) extractable into polar (ethyl acetate) and non-polar (n-pentane and n-heptane) solvents. The obtained soluble fractions were found to consist of mainly simple aliphatic and naphthenic ring structures, while insoluble fractions consisted primarily aromatic compounds. The results were used to draw inferences on the relative utility of different extraction schemes to upgrade vacuum residues as feedstocks for secondary conversion processes in petroleum industry.

引用

页码：249 / 272

页数：24

共 19 条

[11]

MILATOVIC D, 1984, P INT S CHAR HEAV CR, P411

[12] C-13 MAGNETIC-RESONANCE OF COAL-DERIVED LIQUIDS [J].

PUGMIRE, RJ ;

GRANT, DM ;

ZILM, KW ;

ANDERSON, LL ;

OBLAD, AG ;

WOOD, RE .

FUEL, 1977, 56 (03) :295-301

[13]

SAROWHA SLS, 1982, RES IND, V27, P263

[14]

SINGH ID, 1984, P INT S CHAR HEAV CR, P284

[15]

SINGH ID, 1984, PETROCHEM, V87, P128

[16]

SRIVASTAVA SP, 1983, INDIAN J TECHNOL, V21, P191

[17] STRUCTURAL INVESTIGATION ON COLUMN-CHROMATOGRAPHED VACUUM RESIDUES OF VARIOUS PETROLEUM CRUDES BY C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

TAKEGAMI, Y ;

WATANABE, Y ;

SUZUKI, T ;

MITSUDO, TA ;

ITOH, M .

FUEL, 1980, 59 (04) :253-259

[18] A STUDY OF THE STRUCTURE OF PETROLEUM ASPHALTENES AND RELATED SUBSTANCES BY INFRARED-SPECTROSCOPY [J].

YEN, TF ;

WU, WH ;

CHILINGAR, GV .

ENERGY SOURCES, 1984, 7 (03) :203-235

[19] DERIVATION OF STRUCTURAL PARAMETERS FOR COAL-DERIVED OIL BY C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROMETRY [J].

YOSHIDA, T ;

MAEKAWA, Y ;

UCHINO, H ;

YOKOYAMA, S .

ANALYTICAL CHEMISTRY, 1980, 52 (06) :817-820

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