High pressure co-ordination chemistry of a palladium thioether complex:: pressure versus electrons

被引：52

作者：

Allan, David R.

Blake, Alexander J.

Huang, Deguang

Prior, Timothy J.

Schroeder, Martin

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[3] CCLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b606736k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mononuclear Pd(II) complex cis-[PdCl2([9] aneS(3))] ([9] aneS(3) = 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.

引用

收藏

页码：4081 / 4083

页数：3

相关论文

共 25 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] OPTICAL FLUORESCENCE SYSTEM FOR QUANTITATIVE PRESSURE MEASUREMENT IN DIAMOND-ANVIL CELL [J].

BARNETT, JD ;

BLOCK, S ;

PIERMARINI, GJ .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1973, 44 (01) :1-9

[3] CARBOCYCLIC COMPLEXES INCORPORATING MACROCYCLIC LIGANDS - THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURE OF THE BINUCLEAR SPECIES [RH2(ETA-C5ME5)2CL2(1,4,7,10,13,16-HEXATHIACYCLO-OCTADECANE)](BPH4)2 [J].

BELL, MN ;

BLAKE, AJ ;

SCHRODER, M ;

STEPHENSON, TA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (06) :471-472

[4] PI-EFFECTS IN THIOETHER MACROCYCLIC COMPLEXES - THE STABILIZATION AND STRUCTURE OF THE LOW-SPIN FE-3 THIOETHER COMPLEX [FE([9]ANES3)2]3+ [J].

BLAKE, AJ ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1433-1434

[5] [AG2(1,4,7,10,13-PENTATHIACYCLOPENTADECANE)2]2+ - A BINUCLEAR SILVER(I) COMPLEX INCORPORATING ASYMMETRICALLY BRIDGING THIOETHER DONORS [J].

BLAKE, AJ ;

GOULD, RO ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) :974-976

[6] SYNTHESIS, STRUCTURE AND REACTIVITY OF CATIONIC RHODIUM(I) AND IRIDIUM(I) THIOETHER CROWNS - STRUCTURES OF [M([9]ANES3)(COD)]+ (M = RH, IR, COD = CYCLOOCTA-1,5-DIENE) AND [RH([9]ANES3)(C2H4)2]+ ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) [J].

BLAKE, AJ ;

HALCROW, MA ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :253-256

[7] SYNTHESIS, STRUCTURES, AND ELECTROCHEMISTRY OF PALLADIUM AND PLATINUM MACROCYCLIC COMPLEXES OF [18]ANEN2S4 (1,4,10,13-TETRATHIA-7,16-DIAZACYCLO-OCTADECANE) AND ME2[18]ANEN2S4 (7,16-DIMETHYL-1,4,10,13-TETRATHIA-7,16-DIAZACYCLO-OCTADECANE) - SINGLE-CRYSTAL X-RAY STRUCTURES OF [PD(ME2[18]ANEN2S4)][PF6]2.ME2CO, [PD([18]ANEN2S4)][BPH4]2, AND [PD2CL2([18]ANEN2S4)][PF6]2.2MECN [J].

BLAKE, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11) :3363-3373

[8] STABILIZATION OF MONONUCLEAR PALLADIUM(III) - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF THE [PD(L)2]3+ CATION (L=1,4,7-TRITHIACYCLONONANE) [J].

BLAKE, AJ ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (13) :987-988

[9] STRUCTURE OF CIS-[PDCL21,4,7-TRITIACYCLONONANE] [J].

BLAKE, AJ ;

HOLDER, AJ ;

ROBERTS, YV ;

SCHRODER, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :360-361

[10] STRUCTURAL AND ELECTROCHEMICAL STUDIES ON TRITHIA MACROCYCLIC COMPLEXES OF PALLADIUM [J].

BLAKE, AJ ;

HOLDER, AJ ;

HYDE, TI ;

ROBERTS, YV ;

LAVERY, AJ ;

SCHRODER, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 323 (02) :261-270