Luminescent properties of CaMgSi2O6-based phosphors co-doped with different rare earth ions

被引:58
作者
Jiang, L
Chang, C
Mao, D
Feng, C
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai 200030, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China
基金
上海市自然科学基金;
关键词
CaMgSi2O6; afterglow; phosphor; thermally stimulated luminescence;
D O I
10.1016/j.jallcom.2004.01.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rare earth ions doped CaMgSi2O6 photo-luminescent materials with long afterglow were prepared by solid state reaction in a reductive atmosphere. The influence of co-doping rare earth ions (Dy and Nd) on the luminescence of CaMgSi2O6 host was studied. The 438 nm emission of the phosphors can be ascribed to 4f(7)-4f(6)5d interconfiguration transitions of Eu2+ ions, which is caused by the [EuO6] emitting center formed in CaMgSi2O6 host. All of these phosphors have long afterglow phenomenon. Both afterglow intensity and persistent afterglow time of CaMgSi2O6:Eu, Dy are better than those of CaMgSi2O6:Eu and CaMgSi2O6:Eu, Nd, which is in agreement with the results of thermally stimulated luminescence curves. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 215
页数:5
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