Structures of a novel trinuclear palladium(II) dithiocarbamate complex and of bis(diethyldithiocarbamato)dibromopalladium(IV)

被引：14

作者：

Blake, AJ

Kathirgamanathan, P

Toohey, MJ

机构：

[1] S Bank Univ, Sch Elect Elect & Informat Engn, Ctr Elect Mat Engn, London SE1 0AA, England

[2] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England

来源：

INORGANICA CHIMICA ACTA | 2000年 / 303卷 / 01期

关键词：

crystal structures; palladium complexes; dithiocarbamate complexes;

D O I：

10.1016/S0020-1693(99)00521-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Determination of the crystal structure of bis(diethyldithiocarbamato)dibromopalladium(IV) (I), shows it to have a distorted octahedral geometry, with the bromide ligands mutually cis. We also report the structure of a new palladium(II) complex, obtained as a decomposition product in the crystallisation of I, which has three palladium centres coordinated by bridging and terminal dithiocarbamates. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：137 / 139

页数：3

共 5 条

[1]

Beurskens P.T., 1971, J CRYST MOL STRUCT, V1, P253, DOI [10.1007/BF01198537, DOI 10.1007/BF01198537]

[2] SULFUR CHELATES .16. CHEMICAL PROPERTIES OF OXIDIZED NICKEL(II) DITHIOCARBAMATES - X-RAY CRYSTAL-STRUCTURE OF TRIS(N,N-DI-N-BUTYLDITHIOCARBAMATO)NICKEL(IV) BROMIDE, NIC27H54N3S6BR [J].