PHOTOCHEMISTRY OF DITHIOCARBAMATE COMPLEXES OF NI(IV) .2. MECHANISM OF PHOTOCHROMIC TRANSFORMATIONS

被引：9

作者：

PLYUSNIN, VF

GRIVIN, VP

BAZHIN, NM

KUZNETZOVA, EP

LARIONOV, SV

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,RUSSIA

[2] NOVOSIBIRSK INORGAN CHEM INST,NOVOSIBIRSK 630090,RUSSIA

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1993年 / 74卷 / 2-3期

关键词：

D O I：

10.1016/1010-6030(93)80108-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reverse dark processes were studied to observe photochromic transformations in solutions of dithiocarbamate complexes of Ni(IV). The kinetic characteristics of the processes were established and the mechanism of photochromic transformations was proposed. The molecules of the complex were shown to endure more than 10(4) transition cycles.

引用

页码：129 / 135

页数：7

共 10 条

[1]

BARACHEVSKII VA, 1977, FOTOKHROMIZM EGO PRI, P279

[2]

FACKLER JP, 1973, J AM CHEM SOC, V92, P774

[3] PULSED LASER PHOTOLYSIS OF THE PTCL-6-2--CREATININE SYSTEM IN METHANOL [J].