Suzuki Polycondensation: Polyarylenes a la Carte

被引:264
作者
Sakamoto, Junji [1 ]
Rehahn, Matthias [2 ]
Wegner, Gerhard [3 ]
Schlueter, A. Dieter [1 ]
机构
[1] Swiss Fed Inst Technol, Dept Mat, CH-8093 Zurich, Switzerland
[2] Tech Univ Darmstadt, Ernst Berl Inst Chem Engn & Macromol Sci, D-64287 Darmstadt, Germany
[3] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
基金
瑞士国家科学基金会;
关键词
conjugated polymers; OLED materials; polymer synthesis; polyphenylenes; Suzuki-Miyaura cross-coupling; LIGHT-EMITTING-DIODES; CROSS-COUPLING REACTIONS; CATALYST-TRANSFER POLYCONDENSATION; CHAIN-GROWTH POLYMERIZATION; SYNTHETIC RODLIKE POLYELECTROLYTE; CYCLOMETALATED IRIDIUM COMPLEXES; PREFERENTIAL OXIDATIVE ADDITION; CONJUGATED CHELATING POLYMERS; FLUORENE-BASED POLYMERS; HIGH-EFFICIENCY;
D O I
10.1002/marc.200900063
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This review draws a rather comprehensive picture of how Suzuki polycondensation was discovered in 1989 and how it was subsequently developed into the most powerful polymerization method for polyarylenes during the last 20 years. It combines insights into synthetic issues with classes of polymers prepared and touches upon aspects of this method's technological importance. Because a significant part of the developmental work was carried out in industry, the present review makes reference to an unusually large number of patents.
引用
收藏
页码:653 / 687
页数:35
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