Multinuclear NMR studies of tris(oxaalkyl) borates and their complexes with some metal cations

被引：12

作者：

Gierczyk, B ^{[1
]}

Schroeder, G ^{[1
]}

Nowak-Wydra, B ^{[1
]}

Wojciechowski, C ^{[1
]}

Brzezinski, B ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 513卷 / 1-3期

关键词：

tris(oxaalkyl)borates; H-1; C-13; B-11 and O-17 NMR; complexation of metal cations;

D O I：

10.1016/S0022-2860(99)00113-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nuclear magnetic resonance (NMR) of H-1, C-13, B-11 and O-17 nuclei has been used for the study of complexation of CoCl2, NiCl2 and CuCl2 salts with three tris(oxaalkyl) berates. All NMR techniques demonstrated the formation of complexes but the most informative were the C-13 and O-17 NMR measurements. The structures of the complexes formed are discussed in this article. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：149 / 153

页数：5

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