Discovery of a new catalytically active and selective zeolite (ITQ-30) by high-throughput synthesis techniques

被引：68

作者：

Corma, Avelino ^{[1
]}

Diaz-Cabanas, M. Jose ^{[1
]}

Moliner, Manuel ^{[1
]}

Martinez, Cristina ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

来源：

JOURNAL OF CATALYSIS | 2006年 / 241卷 / 02期

关键词：

ITQ-30; HT zeolite synthesis; MWW zeolite family; benzene alkylation to cumene with ITQ-30;

D O I：

10.1016/j.jcat.2006.04.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By applying a sequential design of experiments, high-throughput syntheses, and X-ray diffraction and data-mining techniques, it has been possible to synthesize a new zeolite (ITQ-30) within a wide range of Si/Al ratios (10-infinity). Structurally, ITQ-30 belongs to the MWW family, with disordered layers as MCM-56. Its large external surface area makes this zeolite an active and selective catalyst for alkylation of benzene with propylene. (c) 2006 Elsevier Inc. All rights reserved.

引用

页码：312 / 318

页数：7

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