Synthesis, structure and anion-exchange property of the first example of self-penetrated three-dimensional metal-organic framework with flexible three-connecting ligand and nickel(II) perchlorate

被引：33

作者：

Wan, SY ^{[1
]}

Huang, YT ^{[1
]}

Li, YZ ^{[1
]}

Sun, WY ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2004年 / 73卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

anion exchange; metal-organic framework; self-penetration; nickel(II) complex; three-connecting ligand;

D O I：

10.1016/j.micromeso.2003.12.029

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Novel polymeric coordination complex [Ni(timpt)(2)](ClO4)(2) 1 was synthesized by solvothermal reaction of 2,4,6-tris[4-(imidazol-1-ylmethyl)phenyl]-1,3,5-triazine (timpt) ligand with Ni(ClO4)(2) (.) 6H(2)O and characterized by X-ray crystallography. Each Ni(II) is coordinated by six imidazolyl N atoms from six different timpt ligands with an octahedral geometry and each timpt ligand connects three metal atoms to generate a three-dimensional (3D) metal-organic framework with self-penetration. The uncoordinated perchlorate anions are located within the voids of the 3D structure through C-H-... O hydrogen bonds, which enable the complex to show anion-exchange property. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：101 / 108

页数：8

共 39 条

[21] Functional micropore chemistry of crystalline metal complex-assembled compounds [J].

Kitagawa, S ;

Kondo, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (08) :1739-1753

[22]

Kondo M, 1999, ANGEW CHEM INT EDIT, V38, P140, DOI 10.1002/(SICI)1521-3773(19990115)38:1/2<140::AID-ANIE140>3.0.CO

[23]

2-9

[24] Microporous materials constructed from the interpenetrated coordination networks. Structures and methane adsorption properties [J].

Kondo, M ;

Shimamura, M ;

Noro, S ;

Minakoshi, S ;

Asami, A ;

Seki, K ;

Kitagawa, S .

CHEMISTRY OF MATERIALS, 2000, 12 (05) :1288-1299

[25] A two-dimensional network constructed via 72-membered heart-shaped macrocycles, a copper(II) complex with 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene and diethylenetriamine ligands [J].

Liu, HK ;

Sun, WY ;

Zhu, HL ;

Yu, KB ;

Tang, WX .

INORGANICA CHIMICA ACTA, 1999, 295 (02) :129-135

[26] Self-assembly of the first copper(II) infinite 2D network with large cavities formed between the two adjacent layers [J].

Liu, HK ;

Sun, WY ;

Tang, WX ;

Yamamoto, T ;

Ueyama, N .

INORGANIC CHEMISTRY, 1999, 38 (26) :6313-+

[27] The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres and its encapsulation of a neutral guest molecule [J].

Liu, HK ;

Sun, WY ;

Ma, DJ ;

Yu, KB ;

Tang, WX .

CHEMICAL COMMUNICATIONS, 2000, (07) :591-592

[28] Crystal engineering of multidimensional copper(I) and silver(I) coordination supermolecules and polymers with functions [J].

Munakata, M ;

Wu, LP ;

KurodaSowa, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (08) :1727-1743

[29]

Noro S, 2000, ANGEW CHEM INT EDIT, V39, P2082

[30] Synthesis and characterisation of infinite di- and tri-nuclear zinc co-ordination networks with flexible dipyridyl ligands [J].

Plater, MJ ;

Foreman, MRS ;

Gelbrich, T ;

Hursthouse, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (13) :1995-2000

← 1 2 3 4 →