Hexaaquacobalt(II) bis(2-aminotoluene-4-sulfonate)

被引：22

作者：

Gunderman, BJ ^{[1
]}

Dubey, SN ^{[1
]}

Squattrito, PJ ^{[1
]}

机构：

[1] KURUKSHETRA UNIV,DEPT CHEM,KURUKSHETRA 132119,HARYANA,INDIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196011419

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Co(H2O)(6)](C7H8NO3S)(2), has a structure built of segregated layers of hexaaquacobalt(II) cations and 2-aminotoluene-4-sulfonate anions, The Co atom is in a fairly regular octahedral coordination environment of water molecules [Co-O range 2.046 (3)-2.111 (3) Angstrom]. The anions are arranged with the sulfonate groups directed to opposite faces of the layer in an alternating fashion. The layers are held together by a series of O-H ... O hydrogen bonds between the water molecules and sulfonate O atoms [H ... O range 1.89 (4)-2.10 (4) Angstrom]. The Mn and Zn salts are isostructural. These features are similar to those of other divalent metal organosulfonate salts.

引用

页码：17 / 19

页数：3

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