Hypervalent iodine goes catalytic

被引：439

作者：

Richardson, Robert D. ^{[1
]}

Wirth, Thomas ^{[1
]}

机构：

[1] Univ Cardiff Wales, Sch Chem, Cardiff CF10 3AT, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

catalysis; hypervalent compounds; iodine; oxidation; synthetic methods;

D O I：

10.1002/anie.200601817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dash of iodine: Different reactions relying on the power of hypervalent iodine reagents can now be performed with catalytic amounts of these compounds and a stoichiometric oxidant. Oxidations of alcohols, α-functionalizations of ketones, and spirocyclizations of phenol derivatives are possible. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4402 / 4404

页数：3

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