Versatile hypervalent-iodine(III)-catalyzed oxidations with m-chloroperbenzoic acid as a cooxidant

被引:311
作者
Dohi, T [1 ]
Maruyama, A [1 ]
Yoshimura, M [1 ]
Morimoto, K [1 ]
Tohma, H [1 ]
Kita, Y [1 ]
机构
[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan
关键词
homogeneous catalysis; hypervalent compounds; iodine; oxidation; synthetic methods;
D O I
10.1002/anie.200501688
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) A new and effective use of hypervalent iodine(III) reagents as catalysts involves the transformation of iodoarenes 1 into hypervalent iodine(III) species 2 with meta-chloroperbenzoic acid (mCPBA) as the appropriate cooxidant. With observed turnover numbers greater than 70, this procedure paves the way for broader application of these useful oxidants in organic synthesis. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6193 / 6196
页数:4
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