Versatile hypervalent-iodine(III)-catalyzed oxidations with m-chloroperbenzoic acid as a cooxidant

被引：311

作者：

Dohi, T ^{[1
]}

Maruyama, A ^{[1
]}

Yoshimura, M ^{[1
]}

Morimoto, K ^{[1
]}

Tohma, H ^{[1
]}

Kita, Y ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 38期

关键词：

homogeneous catalysis; hypervalent compounds; iodine; oxidation; synthetic methods;

D O I：

10.1002/anie.200501688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A new and effective use of hypervalent iodine(III) reagents as catalysts involves the transformation of iodoarenes 1 into hypervalent iodine(III) species 2 with meta-chloroperbenzoic acid (mCPBA) as the appropriate cooxidant. With observed turnover numbers greater than 70, this procedure paves the way for broader application of these useful oxidants in organic synthesis. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6193 / 6196

页数：4

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