OXIDATION OF ALKYL AND ARYL IODIDES, PHENYLACETALDEHYDE AND ALKENES BY DIMETHYLDIOXIRANE - REACTION-PRODUCTS AND MECHANISM

被引：32

作者：

BRAVO, A ^{[1
]}

FONTANA, F ^{[1
]}

FRONZA, G ^{[1
]}

MINISCI, F ^{[1
]}

SERRI, A ^{[1
]}

机构：

[1] POLITECN MILAN, DIPARTIMENTO CHIM, I-20131 MILAN, ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 38期

关键词：

D O I：

10.1016/0040-4039(95)01376-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl and aryl iodides are smoothly oxidized to iodosoderivatives and phenylacetaldehyde is oxidized to phenylacetic acid or benzyl acetate by dimethyldioxirane depending on the presence or not of oxygen. These results and the epoxidation or the allylic oxidation of alkenes by the same reagent are explained by a general free-radical mechanism.

引用

页码：6945 / 6948

页数：4

共 18 条

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