Copper-catalyzed aerobic phosphonation of sp3 C-H bonds

被引：231

作者：

Basle, Olivier ^{[1
]}

Li, Chao-Jun ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 27期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

ALPHA-AMINO PHOSPHONATES; ONE-POT SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; OXIDATIVE ALKYLATION; GLYCINE DERIVATIVES; ACTIVATED METHYLENE; MOLECULAR-OXYGEN; ACID; FUNCTIONALIZATION; ADJACENT;

D O I：

10.1039/b905275e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient cross-dehydrogenative-coupling (CDC) between sp(3) C-H and H-P bonds was developed using copper salt as catalyst and molecular oxygen as terminal oxidant; this new methodology provides an easy access to biologically important alpha-aminophosphonates.

引用

页码：4124 / 4126

页数：3

共 54 条

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