Spinel Li[Li1/3Ti5/3]O4 as an anode material for lithium ion batteries

被引：140

作者：

Wang, GX ^{[1
]}

Bradhurst, DH ^{[1
]}

Dou, SX ^{[1
]}

Liu, HK ^{[1
]}

机构：

[1] Univ Wollongong, Inst Superconducting & Elect Mat, Energy Storage Mat Program, Wollongong, NSW 2522, Australia

来源：

JOURNAL OF POWER SOURCES | 1999年 / 83卷 / 1-2期

关键词：

spinel Li[Li1/3Ti5/3]O-4; lithium ion battery; chemical insertion; AC impedance spectroscopy;

D O I：

10.1016/S0378-7753(99)00290-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The spinel Li[Li1/3Ti5/3]O-4 compound was synthesised via a solid-state method and its electrochemical performance in lithium ion cells was examined. Lithium ions intercalate into and deintercalate from Li[Li1/3Ti5/3]O-4 with high reversibility. The spinel Li[Li1/3Ti5/3]O-4 demonstrated a very stable structural characteristic for lithium ion insertion and extraction without passivation on its surface. The spinel Li[Li1/3Ti5/3]O-4 as an anode material was coupled with LiCoO2 and LiMn2O4 as cathodes to construct lithium ion cells. These cells provide 2.4-2.5 V operating voltage and without the safety concerns associated with using lithium metal or carbon anodes. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：156 / 161

页数：6

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