Design of new chiral tetraol host compounds, trans-1,4-bis[3-(o-chlorophenyl)-3-hydroxy-3-phenylprop-1-ynyl]-1,4-dihydroxy-cyclohexa-2,5-diene and its tetrahalogeno derivatives
被引:10
作者:
Toda, F
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机构:Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama
Toda, F
Shinyama, T
论文数: 0引用数: 0
h-index: 0
机构:Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama
Shinyama, T
机构:
[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama
来源:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
|
1997年
/
12期
关键词:
D O I:
10.1039/a701874f
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The title chiral tetraol host and its 2,3,5,6-tetrachloro and -tetrabromo derivatives have been prepared by the addition of the lithium acetylide derived from (R)-(-)-1-(o-chlorophenyl)-1-hydroxy-1-phenylprop-2-yne to benzoquinone, chloranil and bromanil, respectively and by complexation with these chiral host compounds, various kinds of rac-guest compounds have been resolved very efficiently.