Design of new chiral tetraol host compounds, trans-1,4-bis[3-(o-chlorophenyl)-3-hydroxy-3-phenylprop-1-ynyl]-1,4-dihydroxy-cyclohexa-2,5-diene and its tetrahalogeno derivatives

被引:10
作者
Toda, F
Shinyama, T
机构
[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 12期
关键词
D O I
10.1039/a701874f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title chiral tetraol host and its 2,3,5,6-tetrachloro and -tetrabromo derivatives have been prepared by the addition of the lithium acetylide derived from (R)-(-)-1-(o-chlorophenyl)-1-hydroxy-1-phenylprop-2-yne to benzoquinone, chloranil and bromanil, respectively and by complexation with these chiral host compounds, various kinds of rac-guest compounds have been resolved very efficiently.
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页码:1759 / 1761
页数:3
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