Phenylimidopentachloroniobate(V) dianion with N-allylphenylammonium counterion

被引：1

作者：

Polamo, M

Leskela, M

机构：

[1] Inorganic Chemistry Laboratory, Department of Chemistry, University of Helsinki, FIN-00014 Helsinki

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196003319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis[phenyl(2-propenyl)ammonium] pentachloro(phenylimido)niobate(V), (C9H12N)(2) [NbCl5 (C6H5N)], is a product of the reaction of niobium pentachloride and N-allylphenylamine. The coordinated secondary amine loses its allyl group and forms an imino bond to the metal. Unreacted N-allylphenylamine behaves as a proton acceptor and is a counterion in the solid state. In the crystalline state, the asymmetric unit consists of two octahedral pentachloro(phenylimido)niobate(V) dianions and four N-allylphenylammonium cations.

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页码：1631 / 1634

页数：4

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