Radical deuteration of alpha-selenylated-beta-silylsulfoxides.

被引：11

作者：

Angelaud, R ^{[1
]}

Landais, Y ^{[1
]}

机构：

[1] UNIV LAUSANNE,COLL PROPEDEUT,INST CHIM ORGAN,CH-1015 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(96)02307-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The deuteration of alpha-selenylated-beta-silylsulfoxides and alpha-selenylated-beta-tert-butylsulfoxides has been shown to lead, with good levels of diastereocontrols to the formation of syn isomers irrespective of the stereochemistry of the sulfinyl precursors. Our results have been rationalized using transition state models which parallel the Felkin-Anh model. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：233 / 236

页数：4

共 23 条

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