Hollow Fe-containing carbon fibers with tubular tertiary structure: preparation and Li-storage properties

被引:28
作者
Adelhelm, Philipp [2 ]
Hu, Yong-Sheng [1 ,4 ]
Antonietti, Markus [3 ]
Maier, Joachim [4 ]
Smarsly, Bernd M. [5 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
[2] Univ Utrecht, Debye Inst NanoMat Sci, NL-3584 CA Utrecht, Netherlands
[3] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[4] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[5] Univ Giessen, Inst Phys Chem, D-35390 Giessen, Germany
关键词
ELECTRODE MATERIALS; HYDROGEN STORAGE; THERMAL-DECOMPOSITION; NANOTUBES; NANOFIBERS; PERFORMANCE; PLATINUM; CATALYST; COMPOSITES; FILAMENTS;
D O I
10.1039/b818452f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hollow carbon fibers with a defined tubular cross-section were obtained by simply heating poly(styrene) in the presence of iron salts. The structures possess a high content of mesoporosity and macroporosity. The carbon itself is characterized by a well-developed sp(2)-graphene structure. When used as anode material in lithium ion batteries, a remarkably high reversible capacity as high as 860 mAh/g was observed, which is attributed to both the morphology of the carbon and the incorporation of iron species.
引用
收藏
页码:1616 / 1620
页数:5
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