Synthesis, electrochemistry and photoconductivity of oligo- and poly-(1,1'-dihexylferrocenylenes)

被引：64

作者：

Hirao, T

Kurashina, M

Aramaki, K

Nishihara, H

机构：

[1] JRDC,PRESTO,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

[2] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 14期

关键词：

D O I：

10.1039/dt9960002929

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oligo- and poly-(1,1'-dihexylferrocenylenes), more soluble than unsubstituted oligo- and poly-(1,1'-ferrocenylenes), were synthesized by reaction of dihexylfulvalene dianion with [FeCl2(thf)(2)] (thf = tetrahydrofuran). Electrochemical properties of pentamers and a hexamer were revealed and compared with theory for a system with a linear combination of redox centres. Charge-transfer complexes of poly(dihexylferrocenylene) (M = 5000, M/M(n) = 1.2) with tetracyanoethylene and 7,7,8,8-tetracyanoquinodimethane exhibit photoconductivity.

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页码：2929 / 2933

页数：5

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