Concise synthesis of a racemic and diastereomeric mixture of the sex pheromones of Matsucoccus pine scales

被引：165

作者：

Watanabe, H ^{[1
]}

Watanabe, T ^{[1
]}

Kitahara, T ^{[1
]}

Mori, K ^{[1
]}

机构：

[1] SCI UNIV TOKYO, DEPT CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1997年 / 61卷 / 01期

关键词：

sex pheromone; pine scale; Matsucoccus; cyanation of allylic alcohol;

D O I：

10.1271/bbb.61.127

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A short (3-5 steps) synthesis of a racemic and diastereomeric mixture of Matsucoccucs sex pheromones (1-3) is described. The key reaction is Lewis acid-mediated cyanation of symmetric tertiary alcohol 6 to afford common intermediate 7.

引用

页码：127 / 130

页数：4

共 24 条

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