Efficient phosphorescent white OLEDs with high color rendering capability

被引:78
作者
Chang, Chih-Hao [1 ,2 ]
Tien, Kun-Cheng [1 ,2 ]
Chen, Chung-Chia [1 ,2 ]
Lin, Ming-Shiang [1 ,2 ]
Cheng, Hsing-Chieh [1 ,2 ]
Liu, Su-Hao [1 ,2 ]
Wu, Chung-Chih [1 ,2 ]
Hung, Jui-Yi [3 ]
Chiu, Yuan-Chieh [3 ]
Chi, Yun [3 ]
机构
[1] Natl Taiwan Univ, Grad Inst Photon & Optoelect, Dept Elect Engn, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Grad Inst Elect Engn, Taipei 10617, Taiwan
[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
关键词
Iridium; Osmium; Phosphorescence; White OLEDs; Color rendering index; LIGHT-EMITTING DEVICES; EXTERNAL QUANTUM EFFICIENCY; ELECTROPHOSPHORESCENT DEVICES; IRIDIUM(III) COMPLEXES; TRIPLET EXCITONS; BLUE; DIODES; EMISSION; EMITTERS; LAYERS;
D O I
10.1016/j.orgel.2009.11.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
By utilizing a newly developed deep-blue iridium complex along with efficient green and orange-red phosphors, we have successfully demonstrated efficient three-component phosphorescent white-emitting organic light-emitting devices (WOLEDs) with excellent performances. Such WOLEDs were based on the deep-blue phosphorescent OLEDs architecture with double emitting layers and double confining layers; portions of the deep-blue phosphors were selectively replaced with green and orange-red phosphors, thereby forming a structure with the green/orange-red emitting layers sandwiched between the two deep-blue emitting layers. Such three-component phosphorescent WOLEDs yielded a high color rendering index (CRI) of up to 94 and Commission Internationale de l'Eclairage (CIE) coordinates close to the ideal equal-energy white (0.33, 0.33). Furthermore, they exhibited rather stable colors and high CRI over a wide brightness range of 10(2)-10(4) cd/m(2) and yielded electroluminescence efficiencies of up to 10.3%, 24.0 cd/A and 16.4 lm/W for the forward directions. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:412 / 418
页数:7
相关论文
共 33 条
[31]   Organic light-emitting diodes based on charge-neutral Os(II) emitters: generation of saturated red emission with very high external quantum efficiency [J].
Tung, YL ;
Lee, SW ;
Chi, Y ;
Tao, YT ;
Chien, CH ;
Cheng, YM ;
Chou, PT ;
Peng, SM ;
Liu, CS .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (04) :460-464
[32]   Blue-emitting heteroleptic iridium(III) complexes suitable for high-efficiency phosphorescent OLEDs [J].
Yang, Cheng-Han ;
Cheng, Yi-Ming ;
Chi, Yun ;
Hsu, Chia-Jung ;
Fang, Fu-Chuan ;
Wong, Ken-Tsung ;
Chou, Pi-Tai ;
Chang, Chih-Hao ;
Tsai, Ming-Han ;
Wu, Chung-Chih .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (14) :2418-2421
[33]   A remarkable ligand orientational effect in osmium-atom-induced blue phosphorescence [J].
Yu, JK ;
Hu, YH ;
Cheng, YM ;
Chou, PT ;
Peng, SM ;
Lee, GH ;
Carty, AJ ;
Tung, YL ;
Lee, SW ;
Chi, Y ;
Liu, CS .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (24) :6255-6264