Tunable Plasmon Resonances in Two-Dimensional Molybdenum Oxide Nanoflakes

被引:386
作者
Alsaif, Manal M. Y. A. [1 ]
Latham, Kay [2 ]
Field, Matthew R. [3 ]
Yao, David D. [1 ]
Medehkar, Nikhil V. [4 ]
Beane, Gary A. [5 ,6 ]
Kaner, Richard B. [7 ]
Russo, Salvy P. [2 ]
Ou, Jian Zhen [1 ]
Kalantar-zadeh, Kourosh [1 ]
机构
[1] RMIT Univ, Sch Elect & Comp Engn, Melbourne, Vic, Australia
[2] RMIT Univ, Sch Appl Sci, Melbourne, Vic, Australia
[3] RMIT Univ, RMIT Microscopy & Microanal Facil, Melbourne, Vic, Australia
[4] Monash Univ, Dept Mat Engn, Clayton, Vic 3168, Australia
[5] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
[6] Univ Melbourne, Inst Bio21, Parkville, Vic 3052, Australia
[7] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90024 USA
关键词
RAMAN-SPECTROSCOPY; THIN-FILMS; MOO3; REDUCTION; OXIDATION; TRANSITION; ADSORPTION; KINETICS; ALBUMIN; GOLD;
D O I
10.1002/adma.201306097
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Tunable plasmon resonances in suspended 2D molybdenum oxide flakes are demonstrated. The 2D configuration generates a large depolarization factor and the presence of ultra-doping produces visible-light plasmon resonances. The ultra-doping process is conducted by reducing the semiconducting 2D MoO3 flakes using simulated solar irradiation. The generated plasmon resonances can be controlled by the doping levels and the flakes' lateral dimensions, as well as by exposure to a model protein.
引用
收藏
页码:3931 / 3937
页数:7
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