Ionic conductivity of lithium conducting SiO2 gels at room temperature

被引：14

作者：

Wasiucionek, M

Breiter, MW

机构：

[1] Inst. F. Technische Electrochemie, Technische Universität Wien, 1060 Wien

[2] Institute of Physics, Warsaw University of Technology

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1997年 / 27卷 / 09期

关键词：

D O I：

10.1023/A:1018451013177

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Fresh silica gels have been used as hosts for liquid organic lithium electrolytes. The residual liquid inside the fresh gels was exchanged by the solutions of selected lithium salts (lithium hexafluorophosphate, lithium tetrafluoroborate) in organic solvents: propylene carbonate (PC), dimethyl sulfoxide (DMSO), dimethyl formamide (DMF), 1,2-diethoxyethane (DEE) and dimethyl carbonate (DMC). The immersion of the gels in solutions based on DEE, DMF and DMC leads to the fast deterioration of the gels. The gels immersed in the solutions based on PC and DMSO exhibit stable conductivities in the range of 10(-3) Scm(-1) at room temperature. That conductivity is close to the conductivity of the corresponding lithium salt solutions.

引用

页码：1106 / 1110

页数：5

共 30 条

[11] AC COMPLEX IMPEDANCE, DC RESISTIVITY, LI-7 AND NA-23 NMR-STUDIES OF THE LAYERED LI(NA)XMO2O4 SYSTEM [J].