Rotaxanes and catenanes built around octahedral transition metals

被引：96

作者：

Chambron, JC ^{[1
]}

Collin, JP ^{[1
]}

Heitz, V ^{[1
]}

Jouvenot, D ^{[1
]}

Kern, JM ^{[1
]}

Mobian, P ^{[1
]}

Pomeranc, D ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, Lab Chim Minerale, UMR 7513, F-67070 Strasbourg, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 2004卷 / 08期

关键词：

rotaxanes; catenanes; ruthenium; transition metals;

D O I：

10.1002/ejoc.200300341

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transition metals are extremely useful tools for the preparation of rotaxanes and catenanes. Traditionally, copper(I) has played an important role in this field, but recently octahedrally coordinated metal centres such as ruthenium(II), have allowed the preparation of highly functional interlocking ring systems. The present review article will discuss this new approach, which gives access to novel rotaxanes and catenanes. Besides the purely synthetic work described, the potential of the prepared compounds to be used as light-driven molecular machines will be mentioned. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).

引用

页码：1627 / 1638

页数：12

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