Highly electrocatalytic reduction of nitrite ions on a copper nanoparticles thin film

被引:33
作者
Ko, Wen-Yin [1 ]
Chen, Wei-Hung [1 ]
Cheng, Ching-Yuan [2 ]
Lin, Kuan-Jiuh [1 ]
机构
[1] Natl Chung Hsing Univ, Dept Chem, Ctr Nanosci & Nanotechnol, Taichung 402, Taiwan
[2] Natl Synchrotron Res Ctr, Expt Facil Div, Hsinchu 30076, Taiwan
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2009年 / 137卷 / 02期
关键词
Copper nanoparticles; Electrocatalysis; Nitrite; Nitric oxide; ELECTROCHEMICAL SENSOR; OXIDE REDUCTION; IN-SITU; NITRATE; AU; FABRICATION; OXIDATION; AMMONIA; DNA; PD;
D O I
10.1016/j.snb.2009.01.014
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
High dense Cu nanoparticles thin films, with the average size of 25.1 nm, were prepared by electrodeposition Cu nanoparticles on Au electrodes pre-coated 1-decanethiol layers (Cu NPs/thiol/Au). It shows high electrocatalytic capability for the reduction of nitrite ion (NO2-) and exhibits a good reproducibility, which can be utilized as efficient electrochemical sensors. The detection limit of NO2- approaches similar to 10(-7) mM and the response time is fast with the average time of 2 s. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:437 / 441
页数:5
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