Isostructural coordination capsules for a series of 10 different d5-d10 transition-metal ions

被引：130

作者：

Hiraoka, Shuichi

Harano, Koji

Shiro, Motoo

Ozawa, Yoshiki

Yasuda, Nobuhiro

Toriumi, Koshiro

Shionoya, Mitsuhiko ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

[2] Rigaku Corp, Akishima, Tokyo 1968666, Japan

[3] Univ Hyogo, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan

[4] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

关键词：

molecular capsules; NMR spectroscopy; self-assembly; supramolecular chemistry; transition metals;

D O I：

10.1002/anie.200601431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Ten of a kind: A series of {M 6L8} octahedral metallocapsules that are structurally identical except for the metal at the apexes was quantitatively prepared from tris-monodentate ligands L and ten divalent d5-d10 transition-metal ions (see picture). Six CF3SO3 - anions coordinated inside the capsules can be site-selectively replaced with other anionic ligands to functionalize the cavity. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6488 / 6491

页数：4

相关论文

共 28 条

[1] Dicatechol-diimines:: easily accessible ligands for the self-assembly of dinuclear triple-stranded helicates [J].

Albrecht, M ;

Janser, I ;

Kamptmann, S ;

Weis, P ;

Wibbeling, B ;

Fröhlich, R .

DALTON TRANSACTIONS, 2004, (01) :37-43

[2] A metallosupramolecular tetrahedron with a huge internal cavity [J].

Albrecht, M ;

Janser, I ;

Meyer, S ;

Weis, P ;

Fröhlich, R .

CHEMICAL COMMUNICATIONS, 2003, (23) :2854-2855

[3] New supramolecular trigonal prisms from zinc(II)-1,4,7,10-tetraazacyclododecane (cyclen) complexes and trithiocyanurate in aqueous solution [J].

Aoki, S ;

Zulkefeli, M ;

Shiro, M ;

Kimura, E .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4894-4899

[4] High-nuclearity homoleptic and heteroleptic coordination cages based on tetra-capped truncated tetrahedral and cuboctahedral metal frameworks [J].

Argent, SP ;

Adams, H ;

Riis-Johannessen, T ;

Jeffery, JC ;

Harding, LP ;

Ward, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) :72-73

[5] A molecular sphere of octahedral symmetry [J].

Chand, DK ;

Biradha, K ;

Fujita, M ;

Sakamoto, S ;

Yamaguchi, K .

CHEMICAL COMMUNICATIONS, 2002, (21) :2486-2487

[6] Supramolecular catalysis of a unimolecular transformation: Aza-cope rearrangement within a self-assembled host [J].

Fiedler, D ;

Bergman, RG ;

Raymond, KN .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (48) :6748-6751

[7]

Fiedler D., 2004, ANGEW CHEM, V116, P6916

[8] Guest encapsulation and self-assembly of a cavitand-based coordination capsule [J].

Haino, T ;

Kobayashi, M ;

Fukazawa, Y .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (12) :3310-3319

[9] A new self-assembling capsule via metal coordination [J].

Haino, T ;

Kobayashi, M ;

Chikaraishi, M ;

Fukazawa, Y .

CHEMICAL COMMUNICATIONS, 2005, (18) :2321-2323

[10] A self-assembled homooxacalix[3]arene-based dimeric capsule constructed by a PdII-pyridine interaction which shows a novel chiral twisting motion in response to guest inclusion [J].

Ikeda, A ;

Udzu, H ;

Zhong, ZL ;

Shinkai, S ;

Sakamoto, S ;

Yamaguchi, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (17) :3872-3877