Selective TEMPO-catalyzed chemicals vs. electrochemical oxidation of carbohydrate derivatives

被引：25

作者：

Barbier, Maximilien

Breton, Tony

Servat, Karine

Grand, Eric

Kokoh, Boniface

Kovensky, Jose

机构：

[1] Univ Picardie, Fac Sci, CNRS, UMR 6219,Lab Glucides, F-80039 Amiens, France

[2] Univ Poitiers, CNRS, UMR 6503, Lab Catalyse Chim Organ, Poitiers, France

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2006年 / 25卷 / 2-3期

关键词：

TEMPO; selective oxidation; allyl-protected carbohydrates;

D O I：

10.1080/07328300600636819

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

TEMPO-catalyzed electrochemical oxidation of carbohydrate derivatives was performed and compared with chemical oxidation, which requires the use of co-oxidants. Allyl-protected derivatives could be readily oxidized by both methods. Electrochemical selectivE oxidation of primary positions has been adapted to unprotected mono- and oligosaccharides.

引用

页码：253 / 266

页数：14

共 26 条

[1] Selective oxidation of carbohydrates on Nafion®-TEMPO-modified graphite felt electrodes [J].