Synthesis and structure of P,N-heterodifunctional ferrocene ligands and their transition metal complexes for palladium-catalyzed aryl amination reaction

被引：27

作者：

Molina, P

Arques, A

Garcia, A

de Arellano, MCR

机构：

[1] UNIV MURCIA, FAC QUIM, DEPT QUIM ORGAN, E-30071 MURCIA, SPAIN

[2] UNIV MURCIA, FAC QUIM, DEPT QUIM INORGAN, E-30071 MURCIA, SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(97)01807-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Staudinger reaction of the beta-ferrocenylvinylazide I with di- and triphosphines provided a new range of P,N-heterodifunctional ferrocene ligands bearing an iminophosphorane and at least a diphenylphosphino group: reactivity rewards Pd (II) and the ability of the resulting complexes for palladium catalyzed aryl amination reaction is described. (C) 1997 Elsevier Science Ltd.

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页码：7613 / 7616

页数：4

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