A new method for synthesis of allenes, including an optically active form, from aldehydes and alkenyl aryl sulfoxides with carbon-carbon bond-formation

被引：40

作者：

Satoh, T ^{[1
]}

Kuramochi, Y ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(99)01666-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ligand exchange reaction of beta-mesyloxy sulfoxides or beta-acetoxy sulfoxides, which were derived from alkenyl aryl sulfoxides and aldehydes in two steps, with n-BuLi or EtMgBr at low temperature gave allenes in good yields. Optically active allenes were synthesized starting from optically active 2-phenylethenyl p-tolyl sulfoxides. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8815 / 8818

页数：4

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