Activation of carbon nanofibres for hydrogen storage

被引：79

作者：

Blackman, James M. ^{[1
]}

Patrick, John W. ^{[1
]}

Arenillas, Ana ^{[1
]}

Shi, Wei ^{[1
]}

Snape, Colin E. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem Environm & Min Engn, Nottingham Fuel & Energy Ctr, Nottingham NG7 2RD, England

来源：

CARBON | 2006年 / 44卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

carbon nanofibres; activation; adsorption; gas storage;

D O I：

10.1016/j.carbon.2005.11.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present study was aimed to investigate different methods of activation of carbon nanofibres, CNF, in order to determine the beneficial effect on the hydrogen sorption capacities of increasing the surface area. Two activation systems were used: physical activation with CO2 and chemical activation with KOH. A range of potential adsorbents were thus prepared by varying the temperature and time of activation. The structure of the CNF proved more suitable to activation by KOH than by CO2, with the former yielding higher surface area carbons (up to 1000 m(2) g(-1)). The increased surface area, however, did not correspond directly with a proportional increase in hydrogen adsorption capacity. Although high surface areas are important for hydrogen storage by adsorption on solids, it would appear that it is essential that not only the physical, but also the chemical, properties of the adsorbents have to be considered in the quest for carbon based materials, with high hydrogen storage capacities. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1376 / 1385

页数：10

共 11 条

[1]

BLACKMAN JM, UNPUB CARBON

[2] Studies into the storage of hydrogen in carbon nanofibers: Proposal of a possible reaction mechanism [J].