Synthesis, solution and electrochemical behaviour of new aza-crown ethers derived from biphenyl

被引：16

作者：

Costero, AM

Monrabal, E

Andreu, C

Martínez-Máñez, R

Soto, J

Padilla-Tosta, M

Pardo, T

Ochando, LE

Amigó, JM

机构：

[1] Univ Valencia, Fac Farm, Dept Quim Organ, E-46100 Burjassot, Spain

[2] Univ Politecn Valencia, Dept Quim, E-46071 Valencia, Spain

[3] Fac Quim, Secc Dept Geol, Burjassot 46100, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 03期

关键词：

D O I：

10.1039/a906342k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Macrocyclic ligands L-1-L-4 containing biphenyl units have been synthesized. Potentiometric and voltametric studies in the presence and the absence of transition metal cations have been carried out. The relationship between the conformation of the ligand and oxidation states has been also considered. The crystal structure of [HgL2(CN)(2)]. 2Hg(CN)(2) has been elucidated by X-ray diffraction techniques.

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页码：361 / 367

页数：7

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