1,5-hydrogen transfers from carbon to N-tributyltin substituted nitrogen

被引：36

作者：

Kim, S

Yeon, KM

Yoon, KS

机构：

[1] Department of Chemistry, Korea Adv. Inst. Sci. and Technol.

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(97)00779-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,5-H transfers from carbon to N-tributyltin substituted nitrogen proceeded smoothly and were much more efficient than 1,5-H transfers from carbon to ordinary nitrogen. 1,5-Tribuyltin group transfer from carbon to nitrogen and intramolecular addition of an aminyl radical to a nirile group were also observed for the first time. (C) 1997 Elsevier Science Ltd.

引用

页码：3919 / 3922

页数：4

共 29 条

[11]

KIM S, 1969, CHEM LETT, P669

[12] RADICAL REACTIONS OF VINYL EPOXIDES VIA RADICAL TRANSLOCATIONS BY A NOVEL 1,5-NORMAL-BU3SN GROUP OR A 1,5-HYDROGEN-ATOM TRANSFER [J].