Metal-Catalyzed Carboxylation of Organometallic Reagents with Carbon Dioxide

被引：330

作者：

Correa, Arkaitz ^{[1
]}

Martin, Ruben ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 34期

关键词：

carbon dioxide; carboxylation; homogeneous catalysis; organometallics; sustainable chemistry; CROSS-COUPLING REACTION; 1-ALKENYL HALIDES; ARYL CHLORIDES; CO2; ESTERS; INSERTION; ZINC; BIS(PINACOLATO)DIBORON; BORYLATION; COMPLEX;

D O I：

10.1002/anie.200900667

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On course for a C1 source: Highly functionalized carboxylic acids can be conveniently prepared from the carboxylation of organometallic reagents using carbon dioxide as the sole source of carbon. Given the sustainable nature of using carbon dioxide as a C1 source, these novel methods could revolutionize approaches towards the elaboration of complex organic molecules and will probably find industrial applications. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6201 / 6204

页数：4

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