Synthesis of palladium(II) 3d-metal(II) paddlewheel acetate-bridged heterodimetallic complexes: Unexpected catalysis by water molecules

被引：40

作者：

Akhmadullina, Nailya S. ^{[1
]}

Cherkashina, Natalia V. ^{[1
]}

Kozitsyna, Natalia Yu. ^{[1
]}

Stolarov, Igor P. ^{[1
]}

Perova, Elena V. ^{[1
]}

Gekhman, Alexander E. ^{[1
]}

Nefedov, Sergei E. ^{[1
]}

Vargaftik, Michael N. ^{[1
]}

Moiseev, Ilya I. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

Palladium complexes; Heterodimetallic complexes; Kinetics; Reaction mechanism; X-ray structure; ACTIVE-SITE; CARBOXYLATES; MECHANISM; CLUSTER;

D O I：

10.1016/j.ica.2008.09.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study of the reaction kinetics between the trinuclear palladium(II) acetate Pd-3(mu-OOCMe)(6) (1) and the mononuclear 3d-metal (Ni-II, Co-II, Cu-II) acetates in acetic acid under water-specified conditions revealed a fairly complicated reaction mechanism triggered by the primary hydrolytic cleavage of an acetate bridge in molecule 1. The isolated reaction products, as established by X-ray diffraction study, are 1D polymeric complexes {Pd(mu-OOCMe)(4)M(OH2)(HOOCMe)(2)}(n) (M = Ni-II, Co-II, Cu-II, Mn-II, Zn-II) built of the Pd-II-based paddlewheel units [Pd(mu-OOCMe)(4)M] and linked trough the H- bonded H2O and MeCOOH molecules. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1943 / 1951

页数：9

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