Some platinum(II) complexes derived from aromatic alkynes

被引:41
作者
Bruce, MI [1 ]
Davy, J
Hall, BC
van Galen, YJ
Skelton, BW
White, AH
机构
[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
[2] Def Sci & Technol Org, Elect Warfare Div, Edinburgh, SA 5108, Australia
[3] Univ Adelaide, Dept Phys, Adelaide, SA 5005, Australia
[4] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia
关键词
platinum; alkynes; X-ray structure;
D O I
10.1002/aoc.345
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Several trans-platinum(II) complexes, of the type R'-{Pt(PBu3)(2)}-R"-{Pt(PR3)(2)}-R', where R' and R" are groups derived from a series of aromatic alkynes and diynes, have been prepared and characterized. Extensive spectroscopic data for these and other known related complexes are presented. A more precise structural study of trans-Pt(CdropCC(6)H(4)CdropCPh)(2)(PBu3)(2) (cf. Z Kristallogr. 1998; 213: 483) is reported. Copyright (C) 2002 John Wiley Sons, Ltd.
引用
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页码:559 / 568
页数:10
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