Alumina nanopowder production from synthetic Bayer liquor

被引:34
作者
Mazloumi, Mahyar [1 ]
Khalifehzadeh, Razieh [1 ]
Sadrnezhaad, S. K. [1 ]
Arami, Hamed [1 ]
机构
[1] Sharif Univ Technol, Dept Mat Sci & Engn, Ctr Excellence Prod Adv Mat, Tehran 9466, Iran
关键词
D O I
10.1111/j.1551-2916.2006.01285.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Alkoxides are the most common precursors used for the production of alumina nanopowders. These materials are, however, expensive and corrosive. This paper introduces a new method for the production of alumina nanopowders by rapid cooling of a synthetic caustic sodium aluminate solution (Bayer liquor), followed by calcination in the presence of a surface-stabilizing agent like 1,2-dihydroxy-3,5-benzene disulfonic acid disodium salt (Tiron). The powders produced are characterized by differential thermal analysis, XRD, transmission electron microscopy, scanning electron microscope, and Brunauer-Emmet-Teller. A nanopowder of alpha-alumina with an average crystallite size of 27.7 nm and an average particle size of 50 nm is produced.
引用
收藏
页码:3654 / 3657
页数:4
相关论文
共 32 条
[11]  
MENSAH JA, 1998, J COLLOID INTERF SCI, V203, P115
[12]   Influence of oxalic acid on the agglomeration process and total soda content in precipitated Al(OH)3 [J].
Nikolic, I ;
Blecic, D ;
Blagojevic, N ;
Radmilovic, V ;
Kovacevic, K .
JOURNAL OF CRYSTAL GROWTH, 2003, 252 (1-3) :360-366
[13]   Influence of oxalic acid on the kinetics of AI(OH)3 growth from caustic soda solutions [J].
Nikolic, I ;
Blecic, D ;
Blagojevic, N ;
Radmilovic, V ;
Kovacevic, K .
HYDROMETALLURGY, 2004, 74 (1-2) :1-9
[14]   Sintering of α-Al2O3-seeded nanocrystalline γ-Al2O3 powders [J].
Nordahl, CS ;
Messing, GL .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (04) :415-422
[15]   Solubility of boehmite in concentrated sodium hydroxide solutions: model development and assessment [J].
Panias, D ;
Asimidis, P ;
Paspaliaris, I .
HYDROMETALLURGY, 2001, 59 (01) :15-29
[16]   Size-controlled synthesis of alumina nanoparticles from aluminum alkoxides [J].
Park, YK ;
Tadd, EH ;
Zubris, M ;
Tannenbaum, R .
MATERIALS RESEARCH BULLETIN, 2005, 40 (09) :1506-1512
[17]   The influence of organic additives on the crystallization and agglomeration of gibbsite [J].
Paulaime, AM ;
Seyssiecq, I ;
Veesler, S .
POWDER TECHNOLOGY, 2003, 130 (1-3) :345-351
[18]  
Rahaman MN., 2003, CERAMIC PROCESSING S
[19]   Investigation of the unseeded nucleation of gibbsite, Al(OH)3, from synthetic Bayer liquors [J].
Rossiter, DS ;
Fawell, PD ;
Ilievski, D ;
Parkinson, GM .
JOURNAL OF CRYSTAL GROWTH, 1998, 191 (03) :525-536
[20]   Synthesis and catalytic properties of nanostructured aluminas obtained by sol-gel method [J].
Sanchez-Valente, J ;
Bokhimi, X ;
Toledo, JA .
APPLIED CATALYSIS A-GENERAL, 2004, 264 (02) :175-181