Interweaving 3D network with double helical tubes filled by 1D coordination polymer chains

被引:100
作者
Yang, E
Zhang, J
Li, ZJ
Gao, S
Kang, Y
Chen, YB
Wen, YH
Yao, YG [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[3] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, Beijing 100871, Peoples R China
关键词
D O I
10.1021/ic049363g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrothermal reaction of mellitic acid, 4,4'-bipydine, and Cu-(CH3COO)(2).H2O gave rise to a novel 3D supramolecular architecture interpenetrated by three types of coordination polymer motifs. Two independent {[CU2(mellitate)(4,4'-bpy)(H2O)(2)](2-)} 3D polymers incorporating helical substructures were interwoven into a 3D network with double-stranded helical tubes that host 1D linear polymers [Cu(4,4'-bpy)(H2O)4](2+)}(n).
引用
收藏
页码:6525 / 6527
页数:3
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